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(25R)-16β-Acetoxy-3β-bromo-23′,26-epoxy-23′,25-dimethyl-5α-cholest-23,23′-en-6-one dichloromethane monosolvate
The crystal structure of the title compound, C(31)H(45)BrO(5)·CH(2)Cl(2), prepared in six steps from diosgenin, confirmed that the configurations of the stereogenic centers, positions 20S and 25R, remain unchanged during the reaction. The six-membered A, B and C rings have chair conformations. The f...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588813/ https://www.ncbi.nlm.nih.gov/pubmed/23468778 http://dx.doi.org/10.1107/S1600536812043590 |