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(2aR*,5S*,6aS*,8aS*,E)-Ethyl 5-hydroxy-7,7,8a-trimethyl-8-oxo-2,2a,6,6a,7,8,8a,8b-octahydro-1H-pentaleno[1,6-bc]oxepine-4-carboxylate
The title compound, C(17)H(24)O(5), featuring a 2-carbethoxy-3-oxepanone unit in its intramolecularly O—H⋯O hydrogen-bonded enol form, was obtained via [(CF(3)CO(2))(2)Rh](2)-catalysed intramolecular O—H bond insertion in the α-diazo-ω-hydroxy-β-ketoester, ethyl 4-[(1S,3aS,6R,6aS)-6-hydroxy-2,...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588985/ https://www.ncbi.nlm.nih.gov/pubmed/23476221 http://dx.doi.org/10.1107/S1600536812046776 |