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(2aR,5S,6aS,8aS,E)-Ethyl 5-hydroxy-7,7,8a-trimethyl-8-oxo-2,2a,6,6a,7,8,8a,8b-octahydro-1H-pentaleno[1,6-bc]oxepine-4-carboxylate

The title compound, C(17)H(24)O(5), featuring a 2-carbethoxy-3-oxepanone unit in its intramolecularly O—H⋯O hydrogen-bonded enol form, was obtained via [(CF(3)CO(2))(2)Rh](2)-catalysed intramolecular O—H bond insertion in the α-diazo-ω-hydroxy-β-ketoester, ethyl 4-[(1S,3aS,6R,6aS)-6-hydroxy-2,...

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Detalles Bibliográficos
Autores principales:	Mehta, Goverdhan, Kumar, C. S. Ananda, Sen, Saikat
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2012
Materias:	Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3588985/ https://www.ncbi.nlm.nih.gov/pubmed/23476221 http://dx.doi.org/10.1107/S1600536812046776

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