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Enantioselective reduction of ketoimines promoted by easily available (S)-proline derivatives

The behavior of readily synthesized and even commercially available (S)-proline derivatives, was studied in the trichlorosilane-mediated reduction of ketoimines. A small library of structurally and electronically modified chiral Lewis bases was considered; such compounds were shown to promote the en...

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Detalles Bibliográficos
Autores principales: Bonsignore, Martina, Benaglia, Maurizio, Raimondi, Laura, Orlandi, Manuel, Celentano, Giuseppe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3628544/
https://www.ncbi.nlm.nih.gov/pubmed/23616807
http://dx.doi.org/10.3762/bjoc.9.71