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Regio- and stereoselective carbometallation reactions of N-alkynylamides and sulfonamides

The carbocupration reactions of heterosubstituted alkynes allow the regio- and stereoselective formation of vinyl organometallic species. N-Alkynylamides (ynamides) are particularly useful substrates for the highly regioselective carbocupration reaction, as they lead to the stereodefined formation o...

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Detalles Bibliográficos
Autores principales: Minko, Yury, Pasco, Morgane, Chechik, Helena, Marek, Ilan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3628878/
https://www.ncbi.nlm.nih.gov/pubmed/23616793
http://dx.doi.org/10.3762/bjoc.9.57