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Complete σ* intramolecular aromatic hydroxylation mechanism through O(2) activation by a Schiff base macrocyclic dicopper(I) complex
In this work we analyze the whole molecular mechanism for intramolecular aromatic hydroxylation through O(2) activation by a Schiff hexaazamacrocyclic dicopper(I) complex, [Cu(I)(2)(bsH2m)](2+). Assisted by DFT calculations, we unravel the reaction pathway for the overall intramolecular aromatic hyd...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3628990/ https://www.ncbi.nlm.nih.gov/pubmed/23616799 http://dx.doi.org/10.3762/bjoc.9.63 |