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Complete σ* intramolecular aromatic hydroxylation mechanism through O(2) activation by a Schiff base macrocyclic dicopper(I) complex

In this work we analyze the whole molecular mechanism for intramolecular aromatic hydroxylation through O(2) activation by a Schiff hexaazamacrocyclic dicopper(I) complex, [Cu(I)(2)(bsH2m)](2+). Assisted by DFT calculations, we unravel the reaction pathway for the overall intramolecular aromatic hyd...

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Detalles Bibliográficos
Autores principales: Poater, Albert, Solà, Miquel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3628990/
https://www.ncbi.nlm.nih.gov/pubmed/23616799
http://dx.doi.org/10.3762/bjoc.9.63