Reductions of aldehydes and ketones with a readily available N-heterocyclic carbene borane and acetic acid

Acetic acid promotes the reduction of aldehydes and ketones by the readily available N-heterocyclic carbene borane, 1,3-dimethylimidazol-2-ylidene borane. Aldehydes are reduced over 1–24 h at room temperature with 1 equiv of acetic acid and 0.5 equiv of the NHC-borane. Ketone reductions are slower b...

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Detalles Bibliográficos
Autores principales: Lamm, Vladimir, Pan, Xiangcheng, Taniguchi, Tsuyoshi, Curran, Dennis P
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629027/
https://www.ncbi.nlm.nih.gov/pubmed/23616812
http://dx.doi.org/10.3762/bjoc.9.76

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629027/
https://www.ncbi.nlm.nih.gov/pubmed/23616812
http://dx.doi.org/10.3762/bjoc.9.76

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