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Thermal decomposition of [Co(en)(3)][Fe(CN)(6)]∙ 2H(2)O: Topotactic dehydration process, valence and spin exchange mechanism elucidation

BACKGROUND: The Prussian blue analogues represent well-known and extensively studied group of coordination species which has many remarkable applications due to their ion-exchange, electron transfer or magnetic properties. Among them, Co-Fe Prussian blue analogues have been extensively studied due t...

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Detalles Bibliográficos
Autores principales: Trávníček, Zdeněk, Zbořil, Radek, Matiková-Maľarová, Miroslava, Drahoš, Bohuslav, Černák, Juraj
Formato: Online Artículo Texto
Lenguaje:English
Publicado: BioMed Central 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3637566/
https://www.ncbi.nlm.nih.gov/pubmed/23391378
http://dx.doi.org/10.1186/1752-153X-7-28