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[μ-3-(Methylsulfanyl)benzene-1,2-dithiolato-1:2κ(4) S,S′:S,S′]bis[tricarbonyliron(I)]
The title compound, [Fe(2)(C(7)H(6)S(3))(CO)(6)], was prepared as a biomimic for the active site of [FeFe]-hydrogenases. The central Fe(2)S(2) core is in a butterfly conformation and each Fe(I) atom has a pseudo-square-pyramidal coordination by three O atoms and two S atoms. The Fe—Fe distance is 2....
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647810/ https://www.ncbi.nlm.nih.gov/pubmed/23723776 http://dx.doi.org/10.1107/S1600536813009860 |