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[μ-3-(Methylsulfanyl)benzene-1,2-dithiolato-1:2κ(4) S,S′:S,S′]bis[tricarbonyliron(I)]

The title compound, [Fe(2)(C(7)H(6)S(3))(CO)(6)], was prepared as a biomimic for the active site of [FeFe]-hydrogenases. The central Fe(2)S(2) core is in a butterfly conformation and each Fe(I) atom has a pseudo-square-pyramidal coordination by three O atoms and two S atoms. The Fe—Fe distance is 2....

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Detalles Bibliográficos
Autores principales:	Yang, Yong, Wang, Ning, Chen, Lin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2013
Materias:	Metal-Organic Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3647810/ https://www.ncbi.nlm.nih.gov/pubmed/23723776 http://dx.doi.org/10.1107/S1600536813009860

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