Reactivity of iron complexes containing monodentate aminophosphine ligands – Formation of four-membered carboxamido-phospha-metallacycles

Treatment of [FeCp(CO)(2)Cl] with 1 equiv of the amidophosphine ligands Li[R(2)PNR′] (R = Ph, iPr, R′ = iPr, tBu, Cy) afforded complexes of the type [FeCp(CO)(κ(2)(C,P)-(C[bond, double bond]O)–NiPr-PPh(2))] (1a), [FeCp(CO)(κ(2)(C,P)-(C[bond, double bond]O)-NtBu-PPh(2))] (1b), and [FeCp(CO)(κ(2)(C,P)...

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Detalles Bibliográficos
Autores principales: Öztopcu, Özgür, Stöger, Berthold, Mereiter, Kurt, Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier Sequoia 2013
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3655263/
https://www.ncbi.nlm.nih.gov/pubmed/23825866
http://dx.doi.org/10.1016/j.jorganchem.2013.03.027

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3655263/
https://www.ncbi.nlm.nih.gov/pubmed/23825866
http://dx.doi.org/10.1016/j.jorganchem.2013.03.027

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