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Reactivity of iron complexes containing monodentate aminophosphine ligands – Formation of four-membered carboxamido-phospha-metallacycles
Treatment of [FeCp(CO)(2)Cl] with 1 equiv of the amidophosphine ligands Li[R(2)PNR′] (R = Ph, iPr, R′ = iPr, tBu, Cy) afforded complexes of the type [FeCp(CO)(κ(2)(C,P)-(C[bond, double bond]O)–NiPr-PPh(2))] (1a), [FeCp(CO)(κ(2)(C,P)-(C[bond, double bond]O)-NtBu-PPh(2))] (1b), and [FeCp(CO)(κ(2)(C,P)...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Elsevier Sequoia
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3655263/ https://www.ncbi.nlm.nih.gov/pubmed/23825866 http://dx.doi.org/10.1016/j.jorganchem.2013.03.027 |