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Dissociation or Cyclization: Options for a Triad of Radicals Released from Oxime Carbamates
[Image: see text] A set of oxime carbamates having N-alkyl and N,N-dialkyl substituents were prepared via carbonyldiimidazole intermediates. It was shown by EPR spectroscopy that they underwent clean homolysis of their N–O bonds upon UV photolysis. During photolysis of acetophenone O-allylcarbamoyl...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2013
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3656830/ https://www.ncbi.nlm.nih.gov/pubmed/23600463 http://dx.doi.org/10.1021/ja402833w |