Structural Basis for Regioisomerization in the Alkali-Metal-Mediated Zincation (AMMZn) of Trifluoromethyl Benzene by Isolation of Kinetic and Thermodynamic Intermediates

[Image: see text] Performed with a desire to advance knowledge of the structures and mechanisms governing alkali-metal-mediated zincation, this study monitors the reaction between the TMP-dialkylzincate reagent [(TMEDA)Na(TMP)((t)Bu)Zn((t)Bu)] 1 and trifluoromethyl benzene C(6)H(5)CF(3)2. A complica...

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Detalles Bibliográficos
Autores principales: Armstrong, David R., Blair, Victoria L., Clegg, William, Dale, Sophie H., Garcia-Alvarez, Joaquin, Honeyman, Gordon W., Hevia, Eva, Mulvey, Robert E., Russo, Luca
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2010
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3660950/
https://www.ncbi.nlm.nih.gov/pubmed/20568749
http://dx.doi.org/10.1021/ja1038598

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3660950/
https://www.ncbi.nlm.nih.gov/pubmed/20568749
http://dx.doi.org/10.1021/ja1038598

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