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One-Carbon Extrusion from a Tetraazafulvalene. Isolation of Aldehydes and a Study of Their Origin

[Image: see text] Reaction of imidazolylidene-derived enetetramine 2 with aliphatic iodides and bromides (and with aryl iodides bearing alkene-containing side-chains in the ortho-position) leads to formation of aliphatic aldehydes through an unprecedented extrusion of a one-carbon unit from the enet...

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Detalles Bibliográficos
Autores principales: Murphy, John A., Schoenebeck, Franziska, Findlay, Neil J., Thomson, Douglas W., Zhou, Sheng-ze, Garnier, Jean
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2009
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3662391/
https://www.ncbi.nlm.nih.gov/pubmed/19415936
http://dx.doi.org/10.1021/ja8092746