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One-Carbon Extrusion from a Tetraazafulvalene. Isolation of Aldehydes and a Study of Their Origin
[Image: see text] Reaction of imidazolylidene-derived enetetramine 2 with aliphatic iodides and bromides (and with aryl iodides bearing alkene-containing side-chains in the ortho-position) leads to formation of aliphatic aldehydes through an unprecedented extrusion of a one-carbon unit from the enet...
Autores principales: | Murphy, John A., Schoenebeck, Franziska, Findlay, Neil J., Thomson, Douglas W., Zhou, Sheng-ze, Garnier, Jean |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3662391/ https://www.ncbi.nlm.nih.gov/pubmed/19415936 http://dx.doi.org/10.1021/ja8092746 |
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