Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates

[Image: see text] The new dialkyl(aryl) lithium zincates [(THF)(2)Li(C(6)H(4)−OMe)MeZnMe] (4), [(TMEDA)Li(C(6)H(4)−OMe)MeZnMe] (6), [(THF)(3)Li(C(6)H(4)−OMe)(t)BuZn(t)Bu] (7), and [(PMDETA)Li(C(6)H(4)−OMe)(t)BuZn(t)Bu] (8) have been prepared by co-complexation reactions of lithiated anisole with the...

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Detalles Bibliográficos
Autores principales: Clegg, William, Conway, Ben, Hevia, Eva, McCall, Matthew D., Russo, Luca, Mulvey, Robert E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2009
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3662405/
https://www.ncbi.nlm.nih.gov/pubmed/19199628
http://dx.doi.org/10.1021/ja8087168

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3662405/
https://www.ncbi.nlm.nih.gov/pubmed/19199628
http://dx.doi.org/10.1021/ja8087168

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