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Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates
[Image: see text] The new dialkyl(aryl) lithium zincates [(THF)(2)Li(C(6)H(4)−OMe)MeZnMe] (4), [(TMEDA)Li(C(6)H(4)−OMe)MeZnMe] (6), [(THF)(3)Li(C(6)H(4)−OMe)(t)BuZn(t)Bu] (7), and [(PMDETA)Li(C(6)H(4)−OMe)(t)BuZn(t)Bu] (8) have been prepared by co-complexation reactions of lithiated anisole with the...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3662405/ https://www.ncbi.nlm.nih.gov/pubmed/19199628 http://dx.doi.org/10.1021/ja8087168 |