High-spin intermediates of the photolysis of 2,4,6-triazido-3-chloro-5-fluoropyridine

In contrast to theoretical expectations, the photolysis of 2,4,6-triazido-3-chloro-5-fluoropyridine in argon at 5 K gives rise to EPR peaks of just two triplet mononitrenes, two quintet dinitrenes, and a septet trinitrene. EPR spectral simulations in combination with DFT calculations show that obser...

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Detalles Bibliográficos
Autores principales: Chapyshev, Sergei V, Korchagin, Denis V, Neuhaus, Patrik, Sander, Wolfram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678571/
https://www.ncbi.nlm.nih.gov/pubmed/23766785
http://dx.doi.org/10.3762/bjoc.9.83

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678571/
https://www.ncbi.nlm.nih.gov/pubmed/23766785
http://dx.doi.org/10.3762/bjoc.9.83

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