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High-spin intermediates of the photolysis of 2,4,6-triazido-3-chloro-5-fluoropyridine
In contrast to theoretical expectations, the photolysis of 2,4,6-triazido-3-chloro-5-fluoropyridine in argon at 5 K gives rise to EPR peaks of just two triplet mononitrenes, two quintet dinitrenes, and a septet trinitrene. EPR spectral simulations in combination with DFT calculations show that obser...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678571/ https://www.ncbi.nlm.nih.gov/pubmed/23766785 http://dx.doi.org/10.3762/bjoc.9.83 |