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Spectroscopic characterization of photoaccumulated radical anions: a litmus test to evaluate the efficiency of photoinduced electron transfer (PET) processes
Steady-state irradiation in neat acetonitrile of some aromatic nitriles, imides and esters (10(−5)–10(−3) M solution) in the presence of tertiary amines allowed the accumulation of the corresponding radical anions, up to quantitative yield for polysubstituted benzenes and partially with naphthalene...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678633/ https://www.ncbi.nlm.nih.gov/pubmed/23766793 http://dx.doi.org/10.3762/bjoc.9.91 |