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Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines
Predominantly (E)-N-diphenylphosphinyl vinyl aziridines are prepared by a reaction of N-diphenylphosphinyl imines with α-bromoallyllithium in the presence of freshly fused ZnCl(2). These aziridines undergo a ring-opening reaction with a variety of carbon and heteronucleophiles, in good yield, and ge...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678660/ https://www.ncbi.nlm.nih.gov/pubmed/23766800 http://dx.doi.org/10.3762/bjoc.9.98 |