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Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines

Predominantly (E)-N-diphenylphosphinyl vinyl aziridines are prepared by a reaction of N-diphenylphosphinyl imines with α-bromoallyllithium in the presence of freshly fused ZnCl(2). These aziridines undergo a ring-opening reaction with a variety of carbon and heteronucleophiles, in good yield, and ge...

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Detalles Bibliográficos
Autores principales:	Jarvis, Ashley N, McLaren, Andrew B, Osborn, Helen M I, Sweeney, Joseph
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2013
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678660/ https://www.ncbi.nlm.nih.gov/pubmed/23766800 http://dx.doi.org/10.3762/bjoc.9.98

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