Diastereoselective synthesis of nitroso acetals from (S,E)-γ-aminated nitroalkenes via multicomponent [4 + 2]/[3 + 2] cycloadditions promoted by LiCl or LiClO(4)

Chiral nonracemic aminated nitroso acetals were synthesized via diastereoselective multicomponent [4 + 2]/[3 + 2] cycloadditions employing new (S,E)-γ-nitrogenated nitroalkenes 5a–c as heterodienes, ethyl vinyl ether (EVE) as a dienophile, and selected electron-deficient alkenes as 1,3-dipolarophile...

Descripción completa

Detalles Bibliográficos
Autores principales: de Carvalho, Leandro Lara, Burrow, Robert Alan, Pereira, Vera Lúcia Patrocinio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678848/
https://www.ncbi.nlm.nih.gov/pubmed/23766798
http://dx.doi.org/10.3762/bjoc.9.96

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3678848/
https://www.ncbi.nlm.nih.gov/pubmed/23766798
http://dx.doi.org/10.3762/bjoc.9.96

Ejemplares similares