A Palladium-Catalyzed Carbo-oxygenation: The Bielschowskysin Case

[Image: see text] An asymmetric synthesis of an advanced tetracyclic intermediate toward the synthesis of bielschowskysin (1) is described. A biomimetic [2 + 2]-photocyclization was used to establish the cyclobutane core of bielschowskysin. Macrocyclization under Heck conditions led to an unpreceden...

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Detalles Bibliográficos
Autores principales: Himmelbauer, Martin, Farcet, Jean-Baptiste, Gagnepain, Julien, Mulzer, Johann
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3691719/
https://www.ncbi.nlm.nih.gov/pubmed/23724910
http://dx.doi.org/10.1021/ol401285d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3691719/
https://www.ncbi.nlm.nih.gov/pubmed/23724910
http://dx.doi.org/10.1021/ol401285d

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