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A Palladium-Catalyzed Carbo-oxygenation: The Bielschowskysin Case
[Image: see text] An asymmetric synthesis of an advanced tetracyclic intermediate toward the synthesis of bielschowskysin (1) is described. A biomimetic [2 + 2]-photocyclization was used to establish the cyclobutane core of bielschowskysin. Macrocyclization under Heck conditions led to an unpreceden...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2013
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3691719/ https://www.ncbi.nlm.nih.gov/pubmed/23724910 http://dx.doi.org/10.1021/ol401285d |