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Synthesis and catalytic properties of a series of cobalt porphyrins as cytochrome P450 model: the effect of substituents on the catalytic activity

A series of cobalt porphyrins derived from hemin was prepared as cytochrome P450 models. Effects of substituents at the cobalt deuteroporphyrin-propionate side chains are investigated in oxidation of toluene with air to benzaldehyde and benzyl alcohol without the use of solvent and sacrificial co-re...

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Detalles Bibliográficos
Autores principales: Hu, Bingcheng, Sun, Chengguo, Deng, Quanzhi, Liu, Zuliang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer Netherlands 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3701136/
https://www.ncbi.nlm.nih.gov/pubmed/23853521
http://dx.doi.org/10.1007/s10847-012-0205-x