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Selective copper(II) acetate and potassium iodide catalyzed oxidation of aminals to dihydroquinazoline and quinazolinone alkaloids

Copper(II) acetate/acetic acid/O(2) and potassium iodide/tert-butylhydroperoxide systems are shown to affect the selective oxidation of ring-fused aminals to dihydroquinazolines and quinazolinones, respectively. These methods enable the facile preparation of a number of quinazoline alkaloid natural...

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Detalles Bibliográficos
Autores principales: Richers, Matthew T, Zhao, Chenfei, Seidel, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3701376/
https://www.ncbi.nlm.nih.gov/pubmed/23843914
http://dx.doi.org/10.3762/bjoc.9.135