Asymmetric Glyoxylate-Ene Reactions Catalyzed by Chiral Pd(II) Complexes in the Ionic Liquid [bmim][PF(6)]

The room temperature ionic liquid [bmim][PF(6)] was employed as the reaction medium in the asymmetric glyoxylate-ene reaction of α-methyl styrene (4a) with ethyl glyoxylate using chiral palladium(II) complexes as the catalysts. [Pd(S-BINAP)(3,5-CF(3)-PhCN)(2)](SbF(6))(2) (1b) showed the highest cata...

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Detalles Bibliográficos
Autores principales: He, Xi Jun, Shen, Zhen Lu, Mo, Wei Min, Hu, Bao Xiang, Sun, Nan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2007
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3714615/

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3714615/

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