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Synthesis of Tetragonal and Orthorhombic Polymorphs of Hf(3)N(4) by High-Pressure Annealing of a Prestructured Nanocrystalline Precursor

[Image: see text] Hf(3)N(4) in nanocrystalline form is produced by solution phase reaction of Hf(NEtMe)(4) with ammonia followed by low-temperature pyrolysis in ammonia. Understanding of phase behavior in these systems is important because early transition-metal nitrides with the metal in maximum ox...

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Detalles Bibliográficos
Autores principales: Salamat, Ashkan, Hector, Andrew L., Gray, Benjamin M., Kimber, Simon A. J., Bouvier, Pierre, McMillan, Paul F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3715886/
https://www.ncbi.nlm.nih.gov/pubmed/23721167
http://dx.doi.org/10.1021/ja403368b