Preparation of anti-Vicinal Amino Alcohols: Asymmetric Synthesis of d-erythro-Sphinganine, (+)-Spisulosine, and d-ribo-Phytosphingosine

[Image: see text] Two variations of the Overman rearrangement have been developed for the highly selective synthesis of anti-vicinal amino alcohol natural products. A MOM ether-directed palladium(II)-catalyzed rearrangement of an allylic trichloroacetimidate was used as the key step for the preparat...

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Detalles Bibliográficos
Autores principales: Calder, Ewen D. D., Zaed, Ahmed M., Sutherland, Andrew
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3719175/
https://www.ncbi.nlm.nih.gov/pubmed/23795558
http://dx.doi.org/10.1021/jo401211j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3719175/
https://www.ncbi.nlm.nih.gov/pubmed/23795558
http://dx.doi.org/10.1021/jo401211j

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