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Interfacial Bond-Breaking Electron Transfer in Mixed Water–Ethylene Glycol Solutions: Reorganization Energy and Interplay between Different Solvent Modes

[Image: see text] We explore solvent dynamics effects in interfacial bond breaking electron transfer in terms of a multimode approach and make an attempt to interpret challenging recent experimental results (the nonmonotonous behavior of the rate constant of electroreduction of S(2)O(8)(2–) from mix...

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Detalles Bibliográficos
Autores principales: Ismailova, Oksana, Berezin, Alexander S., Probst, Michael, Nazmutdinov, Renat R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3725609/
https://www.ncbi.nlm.nih.gov/pubmed/23768162
http://dx.doi.org/10.1021/jp405097c