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Development of an additive-controlled, SmI(2)-mediated stereoselective sequence: Telescoped spirocyclisation, lactone reduction and Peterson elimination
Studies on SmI(2)-mediated spirocyclisation and lactone reduction culminate in a telescoped sequence in which additives are used to “switch on” individual steps mediated by the electron transfer reagent. The sequence involves the use of two activated SmI(2) reagent systems and a silicon stereocontro...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3740502/ https://www.ncbi.nlm.nih.gov/pubmed/23946841 http://dx.doi.org/10.3762/bjoc.9.163 |