Cargando…

A Lewis acid-promoted Pinner reaction

Carbonitriles and alcohols react in a Lewis acid-promoted Pinner reaction to carboxylic esters. Best results are obtained with two equivalents of trimethylsilyl triflate as Lewis acid. Good yields are achieved with primary alcohols and aliphatic or benzylic carbonitriles, but the straightforward syn...

Descripción completa

Detalles Bibliográficos
Autores principales: Pfaff, Dominik, Nemecek, Gregor, Podlech, Joachim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3740506/
https://www.ncbi.nlm.nih.gov/pubmed/23946857
http://dx.doi.org/10.3762/bjoc.9.179