Mechanistic studies on the CAN-mediated intramolecular cyclization of δ-aryl-β-dicarbonyl compounds

The synthesis of 2-tetralones through the cyclization of δ-aryl-β-dicarbonyl substrates by using CAN is described. Appropriately functionalized aromatic substrates undergo intramolecular cyclizations generating 2-tetralone derivatives in moderate to good yields. DFT computational studies indicate th...

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Detalles Bibliográficos
Autores principales: Casey, Brian M, Sadasivam, Dhandapani V, Flowers II, Robert A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3740710/
https://www.ncbi.nlm.nih.gov/pubmed/23946845
http://dx.doi.org/10.3762/bjoc.9.167

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3740710/
https://www.ncbi.nlm.nih.gov/pubmed/23946845
http://dx.doi.org/10.3762/bjoc.9.167

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