Gas-Phase Reactions of Cationic Vanadium-Phosphorus Oxide Clusters with C(2)H(x) (x=4, 6): A DFT-Based Analysis of Reactivity Patterns

The reactivities of the adamantane-like heteronuclear vanadium-phosphorus oxygen cluster ions [V(x)P(4−x)O(10)](.+) (x=0, 2–4) towards hydrocarbons strongly depend on the V/P ratio of the clusters. Possible mechanisms for the gas-phase reactions of these heteronuclear cations with ethene and ethane...

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Detalles Bibliográficos
Autores principales: Dietl, Nicolas, Zhang, Xinhao, van der Linde, Christian, Beyer, Martin K, Schlangen, Maria, Schwarz, Helmut
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2013
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3743165/
https://www.ncbi.nlm.nih.gov/pubmed/23322620
http://dx.doi.org/10.1002/chem.201203050

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3743165/
https://www.ncbi.nlm.nih.gov/pubmed/23322620
http://dx.doi.org/10.1002/chem.201203050

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