Heterolytic Cleavage of Dihydrogen by an Iron(II) PNP Pincer Complex via Metal–Ligand Cooperation

[Image: see text] The bis-carbonyl Fe(II) complex trans-[Fe(PNP-iPr)(CO)(2)Cl](+) reacts with Zn as reducing agent under a dihydrogen atmosphere to give the Fe(II) hydride complex cis-[Fe(PNP-iPr)(CO)(2)H](+) in 97% isolated yield. A crucial step in this reaction seems to be the reduction of the aci...

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Detalles Bibliográficos
Autores principales: Bichler, Bernhard, Holzhacker, Christian, Stöger, Berthold, Puchberger, Michael, Veiros, Luis F., Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3751463/
https://www.ncbi.nlm.nih.gov/pubmed/23990692
http://dx.doi.org/10.1021/om400241x

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3751463/
https://www.ncbi.nlm.nih.gov/pubmed/23990692
http://dx.doi.org/10.1021/om400241x

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