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Lewis Base Directed Cycloaddition Reactions of 2-Pyrones and Alkynylaluminum Reagents

[Image: see text] In situ generated alkynylaluminum reagents have been utilized in a [4 + 2] cycloaddition with 2-pyrones bearing a Lewis basic donor. The reactions proceed at or below room temperature and with complete regiocontrol. This one-pot method affords diversely substituted aromatic compoun...

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Detalles Bibliográficos
Autores principales: Crépin, Damien F., Harrity, Joseph P. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3766945/
https://www.ncbi.nlm.nih.gov/pubmed/23915340
http://dx.doi.org/10.1021/ol401952k