Cargando…

New Way to Substitute Tetracyanocyclopropanes: One-Pot Cascade Assembling of Carbonyls and Malononitrile by the Only Bromine Direct Action

The new type of the chemical cascade reaction was found: formation of cyclopropanes from carbonyl compounds and CH acid by the only bromine direct action. The action of aqueous bromine on the carbonyl compounds and malononitrile in EtOH-H(2)O solutions in the presence of NaOAc results in the formati...

Descripción completa

Detalles Bibliográficos
Autores principales: Vereshchagin, Anatolii N., Elinson, Michail N., Stepanov, Nikita O., Nikishin, Gennady I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Scholarly Research Network 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3767204/
https://www.ncbi.nlm.nih.gov/pubmed/24052823
http://dx.doi.org/10.5402/2011/469453