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Reaction of pharmacological active tris-(2-hydroxyethyl)ammonium 4-chlorophenylsulfanylacetate with ZnCl(2) or NiCl(2): first conversion of a protic ionic liquid into metallated ionic liquid

The reaction of pharmacological active protic ionic liquid tris-(2-hydroxyethyl)ammonium 4-chlorophenylsulfanylacetate H(+)N(CH(2)CH(2)OH)(3) ∙ ((-)OOCCH(2)SC(6)H(4)Cl-4) (1) with zinc or nickel chloride in a ratio of 2:1 affords stable at room temperature powder-like adducts [H(+)N(CH(2)CH(2)OH)(3)...

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Detalles Bibliográficos
Autores principales: Mirskova, Anna N, Adamovich, Sergey N, Mirskov, Rudolf G, Schilde, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: BioMed Central 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3769891/
https://www.ncbi.nlm.nih.gov/pubmed/23421876
http://dx.doi.org/10.1186/1752-153X-7-34