Production of Tartrates by Cyanide-Mediated Dimerization of Glyoxylate: A Potential Abiotic Pathway to the Citric Acid Cycle

[Image: see text] An abiotic formation of meso- and dl-tartrates in 80% yield via the cyanide-catalyzed dimerization of glyoxylate under alkaline conditions is demonstrated. A detailed mechanism for this conversion is proposed, supported by NMR evidence and (13)C-labeled reactions. Simple dehydratio...

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Detalles Bibliográficos
Autores principales: Butch, Christopher, Cope, Elizabeth D., Pollet, Pamela, Gelbaum, Leslie, Krishnamurthy, Ramanarayanan, Liotta, Charles L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3777280/
https://www.ncbi.nlm.nih.gov/pubmed/23914725
http://dx.doi.org/10.1021/ja405103r

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3777280/
https://www.ncbi.nlm.nih.gov/pubmed/23914725
http://dx.doi.org/10.1021/ja405103r

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