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Flow Giese reaction using cyanoborohydride as a radical mediator

Tin-free Giese reactions, employing primary, secondary, and tertiary alkyl iodides as radical precursors, ethyl acrylate as a radical trap, and sodium cyanoborohydride as a radical mediator, were examined in a continuous flow system. With the use of an automated flow microreactor, flow reaction cond...

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Detalles Bibliográficos
Autores principales: Fukuyama, Takahide, Kawamoto, Takuji, Kobayashi, Mikako, Ryu, Ilhyong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3778382/
https://www.ncbi.nlm.nih.gov/pubmed/24062844
http://dx.doi.org/10.3762/bjoc.9.208