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Aerobic radical multifunctionalization of alkenes using tert-butyl nitrite and water
Water induces a change in the product of radical multifunctionalization reactions of aliphatic alkenes involving an sp(3) C–H functionalization by an 1,5-hydrogen shift using tert-butyl nitrite and molecular oxygen. The reaction without water, reported previously, gives nitrated γ-lactols, whereas t...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3778400/ https://www.ncbi.nlm.nih.gov/pubmed/24062832 http://dx.doi.org/10.3762/bjoc.9.196 |