Computational and experimental approaches to the molecular structure of the HCl adduct of Me(3)PO

The reaction of anhydrous HCl((g)) with trimethyl phosphane oxide yields trimethylhydroxy phosphonium chloride. A crystal structure analysis showed that the prevalent mesomeric structure in the solid state is the phosphonium chloride ion pair. Ab initio calculations in the gas phase cannot reproduce...

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Detalles Bibliográficos
Autores principales: Orthaber, Andreas, Belaj, Ferdinand, Pietschnig, Rudolf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2010
Materias:
Full paper/Mémoire
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3779084/
https://www.ncbi.nlm.nih.gov/pubmed/24068981
http://dx.doi.org/10.1016/j.crci.2010.07.006

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3779084/
https://www.ncbi.nlm.nih.gov/pubmed/24068981
http://dx.doi.org/10.1016/j.crci.2010.07.006

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