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Calcium hexakis(dihydrogenphosphito)stannate(IV), Ca[Sn(H(2)PO(2))(6)], with some remarks on the so-called Ge(2)(H(2)PO(2))(6) structure type
The title compound, Ca[Sn(H(2)PO(2))(6)], was formed after a few days when tin(II) fluoride was allowed to react with phosphinic acid at ambient conditions. The structure consists of chains of Ca(2+) and Sn(4+) cations in octahedral sites with -3 symmetry bridged by bidentate hypophosphite anions....
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3793664/ https://www.ncbi.nlm.nih.gov/pubmed/24109251 http://dx.doi.org/10.1107/S1600536813018205 |