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ArCH(OMe)(2) - a Pt(IV)-catalyst originator for diverse annulation catalysis
We discover an important property of a small molecule ArCH(OMe)(2) which transforms catalytically inactive Pt(II)Br(2) procatalyst in situ to an powerful catalyst Pt(IV)-species for diverse annulation reaction. The powerful catalytic system enables selective activation of C(2)-H/N-H and C(2)-H/C(4)-...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3798883/ https://www.ncbi.nlm.nih.gov/pubmed/24136161 http://dx.doi.org/10.1038/srep02987 |