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ArCH(OMe)(2) - a Pt(IV)-catalyst originator for diverse annulation catalysis

We discover an important property of a small molecule ArCH(OMe)(2) which transforms catalytically inactive Pt(II)Br(2) procatalyst in situ to an powerful catalyst Pt(IV)-species for diverse annulation reaction. The powerful catalytic system enables selective activation of C(2)-H/N-H and C(2)-H/C(4)-...

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Detalles Bibliográficos
Autores principales: Ghosh, Subhadeep, Khamarui, Saikat, Gayen, Krishnanka S., Maiti, Dilip K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3798883/
https://www.ncbi.nlm.nih.gov/pubmed/24136161
http://dx.doi.org/10.1038/srep02987