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Superconductivity in Ca(10)(Ir(4)As(8))(Fe(2)As(2))(5) with Square-Planar Coordination of Iridium

We report the unprecedented square-planar coordination of iridium in the iron iridium arsenide Ca(10)(Ir(4)As(8))(Fe(2)As(2))(5). This material experiences superconductivity at 16 K. X-ray photoemission spectroscopy and first-principles band calculation suggest Ir(II) oxidation state, which yields e...

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Detalles Bibliográficos
Autores principales: Kudo, Kazutaka, Mitsuoka, Daisuke, Takasuga, Masaya, Sugiyama, Yuki, Sugawara, Kento, Katayama, Naoyuki, Sawa, Hiroshi, Kubo, Hiroaki S., Takamori, Kenta, Ichioka, Masanori, Fujii, Tatsuo, Mizokawa, Takashi, Nohara, Minoru
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3813930/
https://www.ncbi.nlm.nih.gov/pubmed/24173038
http://dx.doi.org/10.1038/srep03101