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Superconductivity in Ca(10)(Ir(4)As(8))(Fe(2)As(2))(5) with Square-Planar Coordination of Iridium
We report the unprecedented square-planar coordination of iridium in the iron iridium arsenide Ca(10)(Ir(4)As(8))(Fe(2)As(2))(5). This material experiences superconductivity at 16 K. X-ray photoemission spectroscopy and first-principles band calculation suggest Ir(II) oxidation state, which yields e...
Autores principales: | , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3813930/ https://www.ncbi.nlm.nih.gov/pubmed/24173038 http://dx.doi.org/10.1038/srep03101 |