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Gold(I)-catalyzed 6-endo hydroxycyclization of 7-substituted-1,6-enynes

The cyclization of o-(alkynyl)-3-(methylbut-2-enyl)benzenes, 1,6-enynes having a condensed aromatic ring at C3–C4 positions, has been studied under the catalysis of cationic gold(I) complexes. The selective 6-endo-dig mode of cyclization observed for the 7-substituted substrates in the presence of w...

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Detalles Bibliográficos
Autores principales: Sanjuán, Ana M, Martínez, Alberto, García-García, Patricia, Fernández-Rodríguez, Manuel A, Sanz, Roberto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3817472/
https://www.ncbi.nlm.nih.gov/pubmed/24204437
http://dx.doi.org/10.3762/bjoc.9.263